第111回薬剤師国家試験

$\spc\\\\\\\spc\hspace{7mm}\begin{tikzpicture}[spoke/.style={thick, dash pattern=on 5.34pt off 3.03pt},thickline/.style={line width = 3pt},font=\sffamily\bfseries\Large]\node[] at (0.25,0.07) {\sffamily\bfseries\Large Gd$\raisebox{1mm}{$\bf^{3+}$}$};\draw[spoke] (0,0.27) -- (0,1.67) node[above]{\ \,O$^-$};\draw[spoke] (0,-0.27) -- (0,-1.67) node[below=-1mm]{\ \,O$^-$};\draw[spoke] (0.27,0.27) -- (0.82,0.82) node[above right=-1.5mm]{N};\draw[spoke] (-0.27,0.27) -- (-0.82,0.82) node[above left=-1.5mm]{N};\draw[spoke] (-0.27,-0.27) -- (-0.82,-0.82) node[below left=-1.5mm]{N};\draw[spoke] (0.27,-0.27) -- (0.82,-0.82) node[below right=-1.5mm]{N};\draw[spoke] (-0.57,0) -- (-1.7,0) node[left=-3.5mm]{O$^-$};\draw[spoke] (0.45,0) -- (1.25,0) node[right]{OH};\draw[thickline] (-0.97,1.34) -- (-0.58,2.39) -- (0.58,2.39) -- (0.97,1.34);\draw[thick] (1.29,1.29) -- (2.83,2.83) -- (1.82,3.8) node[above=-1.8mm]{\carbonylrotate{0}} -- (0.28,2.26);\begin{scope}[rotate=90]\draw[thickline] (-0.97,1.34) -- (-0.58,2.39) -- (0.58,2.39) -- (0.97,1.34);\draw[thick] (1.29,1.29) -- (2.83,2.83) -- (1.82,3.8) node[]{\carbonylrotate{90}} -- (0.28,2.26);\end{scope}\begin{scope}[rotate=180]\draw[thickline] (-0.97,1.34) -- (-0.58,2.39) -- (0.58,2.39) -- (0.97,1.34);\draw[thick] (1.29,1.29) -- (2.83,2.83) -- (1.82,3.8) node[above=-1mm]{\carbonylrotate{180}} -- (0.28,2.26);\end{scope}\begin{scope}[rotate=270]\draw[thickline] (-0.97,1.34) -- (-0.58,2.39) -- (0.58,2.39) -- (0.97,1.34);\draw[thick] (1.29,1.29) -- (2.83,2.83) -- (1.82,3.8) node[]{\carbonylrotate{270}} -- (0.28,2.26);\end{scope}\end{tikzpicture}\hspace{7mm}\spc\\\\\\\spc$$\scalebox{1.02}{\spc\hspace{1.17cm}\tetrahedral{0==C;1A==OH;2==$\raisebox{0.5mm}{\scalebox{0.7}{$\bullet$}}$HOH$\bf_2$C;3A==H;4==\tetrahedral{0==C;1A==OH;2==(yl);3A==H;4==\tetrahedral{0==C;1A==H;2==(yl);3A==OH;4==\tetrahedral{0==C;1A==OH;2==(yl);3A==H;4==CH$\bf_2$NHCH$\bf_3$}}}}}$
ガドテル酸メグルミン

\begin{tikzpicture}[
spoke/.style={thick, dash pattern=on 5.34pt off 3.03pt},
thickline/.style={line width = 3pt},
font=\sffamily\bfseries\LARGE
]
\node[] at (0.25,0.07) {\sffamily\bfseries\Large Gd$\raisebox{1mm}{$\bf^{3+}$}$};
\draw[spoke] (0,0.27) -- (0,1.67) node[above]{\ \,O$^-$};
\draw[spoke] (0,-0.27) -- (0,-1.67) node[below=-1mm]{\ \,O$^-$};
\draw[spoke] (0.27,0.27) -- (0.82,0.82) node[above right=-1.5mm]{N};
\draw[spoke] (-0.27,0.27) -- (-0.82,0.82) node[above left=-1.5mm]{N};
\draw[spoke] (-0.27,-0.27) -- (-0.82,-0.82) node[below left=-1.5mm]{N};
\draw[spoke] (0.27,-0.27) -- (0.82,-0.82) node[below right=-1.5mm]{N};
\draw[spoke] (-0.57,0) -- (-1.7,0) node[left=-3.5mm]{O$^-$};
\draw[spoke] (0.45,0) -- (1.25,0) node[right]{OH};
\draw[thickline] (-0.97,1.34) -- (-0.58,2.39) -- (0.58,2.39) -- (0.97,1.34);
\draw[thick] (1.29,1.29) -- (2.83,2.83) -- (1.82,3.8) node[above=-1.8mm]{\carbonylrotate{0}} -- (0.28,2.26);
\begin{scope}[rotate=90]
\draw[thickline] (-0.97,1.34) -- (-0.58,2.39) -- (0.58,2.39) -- (0.97,1.34);
\draw[thick] (1.29,1.29) -- (2.83,2.83) -- (1.82,3.8) node[]{\carbonylrotate{90}} -- (0.28,2.26);
\end{scope}
\begin{scope}[rotate=180]
\draw[thickline] (-0.97,1.34) -- (-0.58,2.39) -- (0.58,2.39) -- (0.97,1.34);
\draw[thick] (1.29,1.29) -- (2.83,2.83) -- (1.82,3.8) node[above=-1mm]{\carbonylrotate{180}} -- (0.28,2.26);
\end{scope}
\begin{scope}[rotate=270]
\draw[thickline] (-0.97,1.34) -- (-0.58,2.39) -- (0.58,2.39) -- (0.97,1.34);
\draw[thick] (1.29,1.29) -- (2.83,2.83) -- (1.82,3.8) node[]{\carbonylrotate{270}} -- (0.28,2.26);
\end{scope}
\end{tikzpicture}

\tetrahedral{0==C;1A==OH;2==$\raisebox{0.5mm}{\scalebox{0.7}{$\bullet$}}$HOH$\bf_2$C;3A==H;
4==\tetrahedral{0==C;1A==OH;2==(yl);3A==H;
4==\tetrahedral{0==C;1A==H;2==(yl);3A==OH;
4==\tetrahedral{0==C;1A==OH;2==(yl);3A==H;
4==CH$\bf_2$NHCH$\bf_3$
}
}
}
}