第111回薬剤師国家試験

$\tdplotsetmaincoords{90}{-30}\begin{tikzpicture}[scale=1,tdplot_main_coords,rotate=-30,declare function = {opc=0.9;Cvdw=1.70 cm; Ovdw=1.52 cm; Hvdw=1.20 cm;vdw=1/5; lw=3;}]\coordinate (H1A) at (2.893, 0.027, 1.572);\coordinate (C1) at (2.313, -0.026, 0.656);\coordinate (H1B) at (2.608, 0.794, 0.012);\coordinate (H1C) at (2.549, -0.956, 0.152);\coordinate (C2) at (0.829, 0.049, 0.960);\coordinate (H2A) at (0.534, -0.769, 1.617);\coordinate (H2B) at (0.594, 0.978, 1.477);\coordinate (O) at (0.124, -0.024, -0.243);\coordinate (C3) at (-1.264, 0.034, -0.109);\coordinate (H3A) at (-1.615, -0.784, 0.519);\coordinate (H3B) at (-1.555, 0.964, 0.380);\coordinate (C4) at (-1.887, -0.055, -1.489);\coordinate (H4A) at (-1.547, 0.766, -2.111);\coordinate (H4B) at (-1.607, -0.985, -1.971);\coordinate (H4C) at (-2.970, -0.012, -1.422);\draw[line width = lw, gray] (C1) -- (C2) -- (O) -- (C3) -- (C4);\foreach \labelx /\labely in {C1/H1A, C1/H1B, C1/H1C, C2/H2A, C2/H2B, C3/H3A, C3/H3B, C4/H4A, C4/H4B, C4/H4C}\draw[line width = lw, Pink1] (\labelx) -- (\labely);\foreach \label in {C1, C2, C3, C4}\shade[ball color = black, opacity=opc] (\label) circle (vdw*Cvdw);\shade[ball color = red, opacity=opc] (O) circle (vdw*Ovdw);\foreach \label in {H1A, H1B, H1C, H2A, H2B, H3A, H3B, H4A, H4B, H4C}\shade[ball color = white, opacity=opc] (\label) circle (vdw*Hvdw);\end{tikzpicture}$　ジエチルエーテル

$\spc\\\octamethylene{}{8W==OH}$　1-オクタノール

$\tetrahedral{0==C;1==H;2==H;3==H;4==\tetrahedral{0==C;1==H;2==(yl);3==H;4==\tetrahedral{0==C;1==H;2==(yl);3==H;4==\tetrahedral{0==C;1==H;2==(yl);3==H;4==\tetrahedral{0==C;1==H;2==(yl);3==H;4==\tetrahedral{0==C;1==H;2==(yl);3==H;4==H}}}}}}$　n-ヘキサン

$\tdplotsetmaincoords{53}{40}\begin{tikzpicture}[scale=1,tdplot_main_coords,rotate=17,declare function = {opc=0.9;CCDC=725245;a=7.589; b=5.819; c=26.982; alpha=90; beta=106.14; gamma=90;Cvdw=1.70 cm; Hvdw=1.20 cm;vdw=1/5; lw=3;}]\coordinate (C1) at (-0.635, 3.346, 8.818);\coordinate (C2) at (-1.468, 2.249, 8.611);\coordinate (C3) at (-1.240, 1.363, 7.566);\coordinate (C4) at (-0.175, 1.555, 6.709);\coordinate (C5) at (0.650, 2.646, 6.892);\coordinate (C6) at (0.423, 3.531, 7.934);\coordinate (C7) at (-0.850, 4.298, 9.961);\coordinate (H2) at (-2.203, 2.105, 9.193);\coordinate (H3) at (-1.821, 0.621, 7.441);\coordinate (H4) at (-0.011, 0.943, 6.000);\coordinate (H5) at (1.379, 2.791, 6.301);\coordinate (H6) at (1.000, 4.278, 8.045);\coordinate (H7A) at (-1.204, 5.145, 9.619);\coordinate (H7B) at (0.003, 4.459 , 10.417);\coordinate (H7C) at (-1.489, 3.908 , 10.593);\foreach \labelx /\labely in {C2/H2, C3/H3, C4/H4, C5/H5, C6/H6, C7/H7A, C7/H7B, C7/H7C}\draw[line width = lw, Pink1] (\labelx) -- (\labely);\draw[line width = lw, green] (C1) -- (C2) -- (C3) -- (C4) -- (C5) -- (C6) -- (C1);\draw[line width = lw, gray] (C1) -- (C7);\foreach \label in {C1, C2, C3, C4, C5, C6, C7}\shade[ball color = black, opacity=opc] (\label) circle (vdw*Cvdw);\foreach \label in {H2, H3, H4, H5, H6, H7B, H7C}\shade[ball color = white, opacity=opc] (\label) circle (vdw*Hvdw);\shade[ball color = white, opacity=1] (H7A) circle (vdw*Hvdw);\end{tikzpicture}$　トルエン

$\tdplotsetmaincoords{30}{90+15}\begin{tikzpicture}[scale=1,tdplot_main_coords,rotate=15,declare function = {opc=0.9;CCDC=687201;a=7.408; b=9.403; c=5.754; alpha=90; beta=90; gamma=90;sg=Pnma;Cvdw=1.70 cm; Nvdw=1.55 cm; Ovdw=1.52 cm; Hvdw=1.20 cm; Bvdw=1.92 cm; Clvdw=1.75 cm; Fvdw=1.47 cm;vdw=1/5; lw=3;}]\coordinate (C) at (0.647, 2.351, 0.105);\coordinate (Cl1) at (1.385, 0.919, 0.806);\coordinate (Cl2) at (0.767, 2.351, -1.622);\coordinate (Cl3) at (1.385, 3.783, 0.806);\coordinate (H) at (-0.252, 2.351, 0.270);\draw[line width = lw, Pink1] (C) -- (H);\foreach \labelx /\labely in {C/Cl1, C/Cl2, C/Cl3}\draw[line width = lw,Gold1] (\labelx) -- (\labely);\shade[ball color = white, opacity=opc] (H) circle (vdw*Hvdw);\shade[ball color = black, opacity=opc] (C) circle (vdw*Cvdw);\foreach \label in {Cl1, Cl2, Cl3}\shade[ball color = green, opacity=opc] (\label) circle (vdw*Clvdw);\end{tikzpicture}$　クロロホルム