問7 立体配座異性体

問7 立体配座異性体

by 孝昌 野中 -

\dtetrastereo{1==CH$\bf_3$;2==H;4==H;1s==\put(30,-342){\exosinglebond{0}};1s==\put(160,-93){H};2s==\put(0,200){H};2s==\put(168,-130){CH$\bf_3$};2s==\put(344,186.5){\exosinglebond{120}};2s==\put(65,187){\exosinglebond{-120}}}\qquad\dtetrastereo{1==CH$\bf_3$;2==H;4==H;1s==\put(30,-342){\exosinglebond{0}};1s==\put(160,-93){CH$\bf_3$};2s==\put(0,200){H};2s==\put(168,-130){H};2s==\put(344,186.5){\exosinglebond{120}};2s==\put(65,185){\exosinglebond{-120}}}\put(-1130,-100){\sffamily\bfseries A}\put(-330,-100){\sffamily\bfseries B}　　ブタン

\dtetrastereo{1==CH$\bf_3$;2==H;4==H;1s==\put(30,-342){\exosinglebond{0}};1s==\put(160,-93){H};2s==\put(0,200){H};2s==\put(168,-130){CH$\bf_3$};2s==\put(344,186.5){\exosinglebond{120}};2s==\put(65,187){\exosinglebond{-120}}}
\qquad
\dtetrastereo{1==CH$\bf_3$;2==H;4==H;1s==\put(30,-342){\exosinglebond{0}};1s==\put(160,-93){CH$\bf_3$};2s==\put(0,200){H};2s==\put(168,-130){H};
2s==\put(344,186.5){\exosinglebond{120}};
2s==\put(65,185){\exosinglebond{-120}}}
\put(-1130,-100){\sffamily\bfseries A}
\put(-330,-100){\sffamily\bfseries B}

　

\spc\\\chair[]{}\raisebox{1.8cm}{\scalebox{1.0}{\put(0,0){\WedgeAsSubst(0,0)(1,-2){100}\PutBondLine(79,-200)(451,-200){3pt}\WedgeAsSubst(530,0)(-1,-2){100}\PutBondLine(0,-1)(201,-120){0.4pt}\PutBondLine(200,-120)(532,-120){0.4pt}\PutBondLine(530,-120)(530,0){0.4pt}}}}\put(-800,150){\sffamily\bfseries A}\put(200,150){\sffamily\bfseries B}\hspace{2cm}\spc　　シクロヘキサン

\chair[]{}
\raisebox{1.8cm}{
\scalebox{1.0}{\put(0,0){\WedgeAsSubst(0,0)(1,-2){100}\PutBondLine(79,-200)(451,-200){3pt}\WedgeAsSubst(530,0)(-1,-2){100}\PutBondLine(0,-1)(201,-120){0.4pt}\PutBondLine(200,-120)(532,-120){0.4pt}\PutBondLine(530,-120)(530,0){0.4pt}}}
}
\put(-800,150){\sffamily\bfseries A}
\put(200,150){\sffamily\bfseries B}

　

\spc\\\sixheterov[a]{2s==\sixheterov[d]{}{6==(yl)}[abcef]}{}[cdef]\sixheterov[ac]{}{}[def]\put(-1080,100){\sffamily\bfseries A}\put(-350,100){\sffamily\bfseries B}\spc　　ブタ-1,2-ジエン

\sixheterov[a]{2s==\sixheterov[d]{}{6==(yl)}[abcef]}{}[cdef]
\sixheterov[ac]{}{}[def]
\put(-1080,100){\sffamily\bfseries A}
\put(-350,100){\sffamily\bfseries B}

　

\Utrigonal{3==H$\bf_3$C;0==\put(-27,-55){\exodoublebond{0}\exosinglebond{-120}};0==\put(110,-190){CH$\bf_3$}}\raisebox{-7mm}{\sixheterov[e]{1==CH$\bf_3$;4==CH$\bf_3$}{}[abc]}\put(-1300,-100){\sffamily\bfseries A}\put(-500,-100){\sffamily\bfseries B}　　2-ブテン

\Utrigonal{3==H$\bf_3$C;0==\put(-27,-55){\exodoublebond{0}\exosinglebond{-120}};0==\put(110,-190){CH$\bf_3$}}
\raisebox{-7mm}{
\sixheterov[e]{1==CH$\bf_3$;4==CH$\bf_3$}{}[abc]
}
\put(-1300,-100){\sffamily\bfseries A}
\put(-500,-100){\sffamily\bfseries B}

　

\chairi{4Sa==CH$\bf_3$;3Sa==CH$\bf_3$}\chair{4Se==CH$\bf_3$;3Se==\put(-40,-10){CH$\bf_3$}}\put(-2400,-100){\sffamily\bfseries A}\put(-700,-100){\sffamily\bfseries B}
trans-1,2-ジメチルシクロヘキサン　　cis-1,2-ジメチルシクロヘキサン

\chairi{4Sa==CH$\bf_3$;3Sa==CH$\bf_3$}
\chair{4Se==CH$\bf_3$;3Se==\put(-40,-10){CH$\bf_3$}}
\put(-2400,-100){\sffamily\bfseries A}
\put(-700,-100){\sffamily\bfseries B}